PEEK: To "peek" at something is to take a quick look at something, to sneak a glance. Little kids like to play the game "peek-a-boo" (I see you!).
There is another word that has the same pronouncitation: pique. This word is quite rare, though, since it is really used only in the phrase to "pique" someone's interest.
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(peek image source - peak image source)
(single image)